Catcher - Hanigan - arbitration eligible in 2014; free agent in 2015
1B - Votto - signed through 2023
2B - Phillips - signed through 2017
SS - Cozart - minimum; arbitration eligible in 2015; free agent in 2018
3B - Frazier - minimum; arbitration eligible in 2015; free agent in 2018
LF - Ludwick - signed through 2015; free agent in 2016
CF - Choo - free agent in 2014
RF - Bruce - signed through 2016; free agent in 2017

SP - Arroyo - free agent in 2014
SP - Cueto - signed through 2014, with a team option at $10M for 2015
SP - Bailey - currently arbitration eligible in 2013 & 2014; free agent in 2015
SP - Latos - currently arbitration eligible in 2013, 2014, & 2015, FA in 2016
SP - Leake - currently arbitration eligible in 2013, '14, '15; FA in 2016

RP - Chapman - signed through 2014; arb eligible in '15 & '16; FA in 2017
RP - Broxton - signed through 2015; FA in 2016
RP - Marshall - signed through 2015; FA in 2016
RP - Masset - free agent in 2014
RP - Arredondo - signed; arb eligible in '14 & '15
RP - Ondrusek - currently arb eligible thru '16; free agent in 2017
RP - Lecure - minimum; arb eligible '14 thru '16; free agent in 2017
RP - Simon - currently arb eligible thru '15; FA in 2016
RP - Hoover - minimum; arb eligible in '16; FA in 2019

OF - Heisey - currently arb eligible thru '16; FA in 2017
C - Mesoraco - minimum; arb eligible in '15; FA in 2018
OF - Paul - arb eligible in '14; FA in 2017
IF - Hannahan - signed thru '14; FA in 2015

Bailey and Latos issues will be next.
Lots of relievers up for arbitration, and also Heisey.

Team is pretty intact for the next 2 years though, atleast.